Review: Synthesis and Characterization of Dye Combination as Photosensitizer Dye-Sensitized Solar Cell

Authors

  • Prima Fitri Rusliani Solar Energy Materials Laboratory, Faculty of Mathematics and Science Education, Universitas Pendidikan Indonesia, Indonesia
  • Eka Cahya Prima Solar Energy Materials Laboratory, Faculty of Mathematics and Science Education, Universitas Pendidikan Indonesia, Indonesia https://orcid.org/0000-0002-7852-5611

DOI:

https://doi.org/10.12928/irip.v7i1.6708

Keywords:

Dye Combination, DSSC, Photosensitizer

Abstract

The growing energy demand has driven extensive research into developing renewable technologies. Among these innovations is the production of Dye-Sensitized Solar Cells (DSSCs) utilizing photosensitizers derived from natural materials that are readily available, easy to extract, and environmentally sustainable. Although their efficiency is lower than that of synthetic alternatives, blending natural pigments enhances the absorption spectrum. The combined pigments yield higher efficiency than individual dyes. This review examines the synthesis and characterization processes for using combined dyes as photosensitizers in DSSCs, covering stages such as dye extraction, TiO2 deposition, and various analytical tools. Additionally, it highlights research findings that suggest promising avenues for future exploration in dye combinations.

References

T. Shanmugapriya and J. Balavijayalakshmi, "Efficiency studies of Galinsoga parviflora pigments as a sensitizer in Pt free graphene oxide/nickel oxide counter electrode: dye sensitized solar cell applications," Journal of Cluster Science, vol. 32, pp. 1277-1288, 2021.

E. Cahya Prima, B. Yuliarto, S. Suyatman, and H. K. Dipojono, "Theoretical investigation of anthocyanidin aglycones as photosensitizers for dye-sensitized TiO2 solar cells," Advanced Materials Research, vol. 1112, pp. 317-320, 2015.

G. W. P. Adhyaksa, E. C. Prima, D. K. Lee, I. Ock, S. Yatman, B. Yuliarto, et al., "A Light Harvesting Antenna Using Natural Extract Graminoids Coupled with Plasmonic Metal Nanoparticles for Bio‐Photovoltaic Cells," Advanced Energy Materials, vol. 4, p. 1400470, 2014.

S. Qu, J. Hua, and H. Tian, "New D-π-A dyes for efficient dye-sensitized solar cells," Science China Chemistry, vol. 55, pp. 677-697, 2012.

B. O'regan and M. Grätzel, "A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films," nature, vol. 353, pp. 737-740, 1991.

A. Supriyanto, F. Nurosyid, and A. Ahliha, "Carotenoid pigment as sensitizers for applications of dye-sensitized solar cell (DSSC)," in IOP Conference Series: Materials Science and Engineering, 2018, p. 012060.

D. Rizali, H. Suryanto, and S. Sukarni, "The effect of chlorophyll concentration from papaya leaves on the performance of dye sensitized solar cell," Journal of Mechanical Engineering Science and Technology (JMEST), vol. 3, pp. 59-69, 2020.

M. Wang, C. Grätzel, S. M. Zakeeruddin, and M. Grätzel, "Recent developments in redox electrolytes for dye-sensitized solar cells," Energy & Environmental Science, vol. 5, pp. 9394-9405, 2012.

F. Zanjanchi and J. Beheshtian, "Natural pigments in dye-sensitized solar cell (DSSC): a DFT-TDDFT study," Journal of the Iranian Chemical Society, vol. 16, pp. 795-805, 2019.

R. Syafinar, N. Gomesh, M. Irwanto, M. Fareq, and Y. Irwan, "Chlorophyll pigments as nature based dye for dye-sensitized solar cell (DSSC)," Energy Procedia, vol. 79, pp. 896-902, 2015.

C. Santos-Buelga, N. Mateus, and V. De Freitas, "Anthocyanins. Plant pigments and beyond," vol. 62, ed: ACS Publications, 2014, pp. 6879-6884.

S. Susanto, B. A. Saputra, N. Rosita, and A. Yulianto, "Analisis Spektrum Absorbansi Pigmen Flavonoid Dari Daun Tanaman Andong (Cordyline Fruticosa L.) Sebagai Dye Solar Sel," Jurnal Fisika Unnes, vol. 4, p. 79687, 2014.

R. Hemmatzadeh and A. Jamali, "Enhancing the optical absorption of anthocyanins for dye-sensitized solar cells," Journal of Renewable and Sustainable Energy, vol. 7, 2015.

H. K. Lichtenthaler and C. Buschmann, "Chlorophylls and carotenoids: Measurement and characterization by UV‐VIS spectroscopy," Current protocols in food analytical chemistry, vol. 1, pp. F4. 3.1-F4. 3.8, 2001.

H. S. Maleta, R. Indrawati, L. Limantara, and T. H. P. Brotosudarmo, "Ragam metode ekstraksi karotenoid dari sumber tumbuhan dalam dekade terakhir (telaah literatur)," Jurnal Rekayasa Kimia & Lingkungan, vol. 13, pp. 40-50, 2018.

L. Guidi, M. Tattini, and M. Landi, "How does chloroplast protect chlorophyll against excessive light," Chlorophyll, vol. 21, pp. 21-36, 2017.

H. Hassan, Z. H. Z. Abidin, F. Chowdhury, and A. K. Arof, "A high efficiency chlorophyll sensitized solar cell with quasi solid PVA based electrolyte," International journal of photoenergy, vol. 2016, 2016.

Z. Arifin, S. Soeparman, D. Widhiyanuriyawan, Suyitno, and A. T. Setyaji, "Improving stability of chlorophyll as natural dye for dye-sensitized solar cells," Jurnal Teknologi, vol. 80, pp. 27-33, 2018.

S. Shalini, S. Prasanna, T. K. Mallick, and S. Senthilarasu, "Review on natural dye sensitized solar cells: Operation, materials and methods," Renewable and Sustainable Energy Reviews, vol. 51, pp. 1306-1325, 2015.

A. Hariyadi, M. A. Swasono, and A. C. Augusty, "Combination of dragon fruit, hibiscus and bitterleaf as dye sensitizer to increase efficiency of DSSC," Int. J. Adv. Sci. Eng. Inf. Technol, vol. 7, pp. 936-942, 2017.

I. Hamberg and C. G. Granqvist, "Evaporated Sn‐doped In2O3 films: Basic optical properties and applications to energy‐efficient windows," Journal of Applied Physics, vol. 60, pp. R123-R160, 1986.

G. Calogero, A. Bartolotta, G. Di Marco, A. Di Carlo, and F. Bonaccorso, "Vegetable-based dye-sensitized solar cells," Chemical Society Reviews, vol. 44, pp. 3244-3294, 2015.

B.-K. Koo, D.-Y. Lee, H.-J. Kim, W.-J. Lee, J.-S. Song, and H.-J. Kim, "Seasoning effect of dye-sensitized solar cells with different counter electrodes," Journal of Electroceramics, vol. 17, pp. 79-82, 2006.

A. Pandikumar, S. Murugesan, and R. Ramaraj, "Functionalized silicate sol− gel-supported TiO2− Au core− shell nanomaterials and their photoelectrocatalytic activity," ACS applied materials & interfaces, vol. 2, pp. 1912-1917, 2010.

A. Fukui, R. Komiya, R. Yamanaka, A. Islam, and L. Han, "Effect of a redox electrolyte in mixed solvents on the photovoltaic performance of a dye-sensitized solar cell," Solar Energy Materials and Solar Cells, vol. 90, pp. 649-658, 2006.

K. Fukui, T. Yonezawa, and H. Shingu, "A molecular orbital theory of reactivity in aromatic hydrocarbons," The Journal of Chemical Physics, vol. 20, pp. 722-725, 1952.

D. A. Gaal, J. E. McGarrah, F. Liu, J. E. Cook, and J. T. Hupp, "Nonadiabatic electron transfer at the nanoscale tin-oxide semiconductor/aqueous solution interface," Photochemical & Photobiological Sciences, vol. 3, pp. 240-245, 2004.

S. C. Ezike, C. N. Hyelnasinyi, M. A. Salawu, J. F. Wansah, A. N. Ossai, and N. N. Agu, "Synergestic effect of chlorophyll and anthocyanin Co-sensitizers in TiO2-based dye-sensitized solar cells," Surfaces and Interfaces, vol. 22, p. 100882, 2021.

R. Zainul and L. Isara, "Preparation of Dye Sensitized Solar Cell (DSSC) using anthocyanin color dyes from jengkol shell (Pithecellobium lobatum Benth.) by the gallate acid copigmentation," in Journal of Physics: Conference Series, 2019, p. 012021.

E. C. Prima, H. S. Nugroho, G. Refantero, C. Panatarani, and B. Yuliarto, "Performance of the dye-sensitized quasi-solid state solar cell with combined anthocyanin-ruthenium photosensitizer," RSC advances, vol. 10, pp. 36873-36886, 2020.

E. Prima, B. Yuliarto, and H. Dipojono, "Charge Transfer Dynamics of Highly Efficient Cyanidin-3-O-Glucoside Sensitizer for Dye-Sensitized Solar Cells," in Journal of Physics: Conference Series, 2016, p. 012031.

H. Bahtiar, N. A. Wibowo, and F. S. Rondonuwu, "Konstruksi sel surya bio menggunakan campuran klorofil-karotenoid sebagai sensitizer," Jurnal Fisika dan Aplikasinya, vol. 11, pp. 19-23, 2015.

A. Lim, N. Haji Manaf, K. Tennakoon, R. Chandrakanthi, L. B. L. Lim, J. Bandara, et al., "Higher performance of DSSC with dyes from Cladophora sp. as mixed cosensitizer through synergistic effect," Journal of Biophysics, vol. 2015, 2015.

E. Prima, "Studi Performansi Natural Dye Sensitized Solar Cell Menggunakan Fotoelektrode TiO2 Nanopartikel," Thesis, Institut Teknologi Bandung, 2013.

K. Erande, P. Hawaldar, S. Suryawanshi, B. Babar, A. Mohite, H. Shelke, et al., "Extraction of natural dye (specifically anthocyanin) from pomegranate fruit source and their subsequent use in DSSC," Materials Today: Proceedings, vol. 43, pp. 2716-2720, 2021.

A. Orona-Navar, I. Aguilar-Hernández, T. López-Luke, A. Pacheco, and N. Ornelas-Soto, "Dye sensitized solar cell (DSSC) by using a natural pigment from microalgae," International Journal of Chemical Engineering and Applications, vol. 11, p. 14, 2020.

I. Hikmah and G. Prajitno, "Pengaruh Penggunaan Gel-Electrolyte pada Prototipe Dye Sensitized Solar Cell (DSSC) berbasis TiO2 Nanopartikel dengan Ekstrak Murbei (Morus) sebagai Dye Sensitizer pada Substrat Kaca ITO," Jurnal Sains dan Seni ITS, vol. 4, pp. B5-B10, 2015.

D. Barpuzary, A. S. Patra, J. V. Vaghasiya, B. G. Solanki, S. S. Soni, and M. Qureshi, "Highly efficient one-dimensional ZnO nanowire-based dye-sensitized solar cell using a metal-free, D− π− A-type, carbazole derivative with more than 5% power conversion," ACS Applied Materials & Interfaces, vol. 6, pp. 12629-12639, 2014.

D. Ganta, K. Combrink, and R. Villanueva, "Natural dye-sensitized solar cells: fabrication, characterization, and challenges," in Advances in Solar Energy Research, ed: Springer, 2018, pp. 129-155.

T. K. Das, P. Ilaiyaraja, and C. Sudakar, "Whispering gallery mode assisted enhancement in the power conversion efficiency of DSSC and QDSSC devices using TiO2 microsphere photoanodes," ACS Applied Energy Materials, vol. 1, pp. 765-774, 2018.

B. Rezaei, I. Mohammadi, A. A. Ensafi, and M. M. Momeni, "Enhanced efficiency of DSSC through AC-electrophoretic hybridization of TiO2 nanoparticle and nanotube," Electrochimica Acta, vol. 247, pp. 410-419, 2017.

A. Orona-Navar, I. Aguilar-Hernández, A. Cerdán-Pasarán, T. López-Luke, M. Rodríguez-Delgado, D. Cárdenas-Chávez, et al., "Astaxanthin from Haematococcus pluvialis as a natural photosensitizer for dye-sensitized solar cell," Algal Research, vol. 26, pp. 15-24, 2017.

P. Joshi, Y. Xie, M. Ropp, D. Galipeau, S. Bailey, and Q. Qiao, "Dye-sensitized solar cells based on low cost nanoscale carbon/TiO 2 composite counter electrode," Energy & Environmental Science, vol. 2, pp. 426-429, 2009.

D. A. Haryanto, S. Landuma, and A. Purwanto, "Fabrication of dye-sensitized solar cell (DSSC) using annato seeds (Bixa orellana Linn)," in AIP Conference Proceedings, 2014, pp. 104-108.

H. Hardani, L. M. Angraeni, C. Cari, and A. Supriyanto, "Improved Performance of Dye-Sensitized Solar Cells With TiO2 Nano-Particles by Using The Carrot as a Dye Solar Cell Application," Jurnal Fisika Flux: Jurnal Ilmiah Fisika FMIPA Universitas Lambung Mangkurat, vol. 16, pp. 61-68, 2019.

S. A. Pataya, P. L. Gareso, and E. Juarlin, "Karakterisasi Lapisan Tipis Titanium Dioksida (TiO2) yang Ditumbuhkan dengan Metode Spin Coating Diatas Substrat Kaca," Jurnal kimia, pp. 1-8, 2016.

K. Hemalatha, S. Karthick, C. J. Raj, N.-Y. Hong, S.-K. Kim, and H.-J. Kim, "Performance of Kerria japonica and Rosa chinensis flower dyes as sensitizers for dye-sensitized solar cells," Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, vol. 96, pp. 305-309, 2012.

D. Dahlan, T. S. Leng, and H. Aziz, "Dye sensitized solar cells (dssc) dengan sensitiser dye alami daun pandan, akar kunyit dan biji beras merah (black rice)," Jurnal Ilmu Fisika| Universitas Andalas, vol. 8, pp. 1-8, 2016.

H. Chang and Y.-J. Lo, "Pomegranate leaves and mulberry fruit as natural sensitizers for dye-sensitized solar cells," Solar energy, vol. 84, pp. 1833-1837, 2010.

G. Richhariya, A. Kumar, P. Tekasakul, and B. Gupta, "Natural dyes for dye sensitized solar cell: A review," Renewable and Sustainable Energy Reviews, vol. 69, pp. 705-718, 2017.

S. S. Hegedus and A. Luque, "Status, trends, challenges and the bright future of solar electricity from photovoltaics," Handbook of photovoltaic science and engineering, pp. 1-43, 2003.

F. Bella, J. Popovic, A. Lamberti, E. Tresso, C. Gerbaldi, and J. Maier, "Interfacial effects in solid–liquid electrolytes for improved stability and performance of dye-sensitized solar cells," ACS applied materials & interfaces, vol. 9, pp. 37797-37803, 2017.

S. S. Nemala, P. Kartikay, S. Prathapani, H. M. Bohm, P. Bhargava, S. Bohm, et al., "Liquid phase high shear exfoliated graphene nanoplatelets as counter electrode material for dye-sensitized solar cells," Journal of colloid and interface science, vol. 499, pp. 9-16, 2017.

D. Zhang, X. Li, H. Li, S. Chen, Z. Sun, X. Yin, et al., "Graphene-based counter electrode for dye-sensitized solar cells," Carbon, vol. 49, pp. 5382-5388, 2011.

X. Meng, C. Yu, X. Song, Z. Liu, B. Lu, C. Hao, et al., "Rational design and fabrication of sulfur-doped porous graphene with enhanced performance as a counter electrode in dye-sensitized solar cells," Journal of Materials Chemistry A, vol. 5, pp. 2280-2287, 2017.

S. Ganesan, P. Karthika, R. Rajarathinam, M. Arthanareeswari, V. Mathew, and P. Maruthamuthu, "A poly (ethylene oxide), poly (vinylidene fluoride) and polycapro lactone polymer blend doped with an indigenous nitrogen–sulfur based organic compound as a novel electrolyte system for dye-sensitized solar cell applications," Solar Energy, vol. 135, pp. 84-91, 2016.

N. Latip, H. Ng, N. Farah, K. Ramesh, and S. Ramesh, "Novel development towards preparation of highly efficient ionic liquid based co-polymer electrolytes and its application in dye-sensitized solar cells," Organic Electronics, vol. 41, pp. 33-41, 2017.

S. Pengfei, P. Bingkun, Z. Jie, W. Yun, Z. Fayun, R. Senlin, et al., "Multi-component eutectic salts to enhance the conductivity of solvent-free ionic liquid electrolytes for dye-sensitized solar cells," Electrochimica Acta, vol. 314, pp. 219-226, 2019.

S. Sadikin, M. Rahman, A. Umar, and M. Salleh, "Effect of spin-coating cycle on the properties of TiO2 thin film and performance of DSSC," International Journal of Electrochemical Science, vol. 12, pp. 5529-5538, 2017.

E. C. Prima, M. Al Qibtiya, B. Yuliarto, Suyatman, and H. K. Dipojono, "Influence of anthocyanin co-pigment on electron transport and performance in black rice dye-sensitized solar cell," Ionics, vol. 22, pp. 1687-1697, 2016.

C. Sreekala, I. Jinchu, K. Sreelatha, Y. Janu, N. Prasad, M. Kumar, et al., "Influence of solvents and surface treatment on photovoltaic response of DSSC based on natural curcumin dye," IEEE Journal of Photovoltaics, vol. 2, pp. 312-319, 2012.

J. Bredas, R. Silbey, D. Boudreaux, and R. Chance, "Chain-length dependence of electronic and electrochemical properties of conjugated systems: polyacetylene, polyphenylene, polythiophene, and polypyrrole," Journal of the American Chemical Society, vol. 105, pp. 6555-6559, 1983.

G. Britton, "Carotenoid research: History and new perspectives for chemistry in biological systems," Biochimica et Biophysica Acta (BBA)-Molecular and Cell Biology of Lipids, vol. 1865, p. 158699, 2020.

M. F. H. Khan, "Design & Experiment of An Integrated Agro-Voltaic Solar PV System," Institute of Energy, University of Dhaka.

K. Wongcharee, V. Meeyoo, and S. Chavadej, "Dye-sensitized solar cell using natural dyes extracted from rosella and blue pea flowers," Solar Energy Materials and Solar Cells, vol. 91, pp. 566-571, 2007.

F. Kabir, M. Bhuiyan, M. Manir, M. Rahaman, M. Khan, and T. Ikegami, "Development of dye-sensitized solar cell based on combination of natural dyes extracted from Malabar spinach and red spinach," Results in Physics, vol. 14, p. 102474, 2019.

A. Ahliha, F. Nurosyid, A. Supriyanto, and T. Kusumaningsih, "The chemical bonds effect of anthocyanin and chlorophyll dyes on TiO2 for dye-sensitized solar cell (DSSC)," in Journal of Physics: Conference Series, 2017, p. 012013.

C. Pathak, K. Surana, V. K. Shukla, and P. K. Singh, "Fabrication and characterization of dye sensitized solar cell using natural dyes," Materials Today: Proceedings, vol. 12, pp. 665-670, 2019.

F. Kabir, M. Bhuiyan, M. Hossain, H. Bashar, M. Rahaman, M. Manir, et al., "Improvement of efficiency of Dye Sensitized Solar Cells by optimizing the combination ratio of Natural Red and Yellow dyes," Optik, vol. 179, pp. 252-258, 2019.

P. Sanjay, K. Deepa, J. Madhavan, and S. Senthil, "Performance of TiO2 based dye-sensitized solar cells fabricated with dye extracted from leaves of Peltophorum pterocarpum and Acalypha amentacea as sensitizer," Materials Letters, vol. 219, pp. 158-162, 2018.

D. Pratiwi, F. Nurosyid, A. Supriyanto, and R. Suryana, "Performance improvement of dye-sensitized solar cells (DSSC) by using dyes mixture from chlorophyll and anthocyanin," in Journal of Physics: Conference Series, 2017, p. 012025.

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2024-06-29

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